银纳米颗粒修饰TiO2薄膜的结构,光学及光催化性能
DOI:
CSTR:
作者:
作者单位:

(曲阜师范大学 山东省激光偏光与信息技术重点实验室,山东 曲阜 273165)

作者简介:

郝殿中(1963-) 男,山东聊城人,工学学士,副教授,主要从事 光学薄膜及相关领域研究等.

通讯作者:

中图分类号:

基金项目:

山东省自然科学金面上项目(ZR2018MD015)资助项目 (曲阜师范大学 山东省激光偏光与信息技术重点实验室,山东 曲阜 273165)


Structural,optical and photocatalytic properties of TiO2films decorated with Ag nanoparticles
Author:
Affiliation:

(Shandong Provincial Key Laboratory of Laser Polarization and Information Techno logy,Qufu Normal University,Qufu 273165,China)

Fund Project:

  • 摘要
  • |
  • 图/表
  • |
  • 访问统计
  • |
  • 参考文献
  • |
  • 相似文献
  • |
  • 引证文献
  • |
  • 资源附件
  • |
  • 文章评论
    摘要:

    采用电子束沉积技术在石英玻璃、硅片基板上沉积了TiO2薄膜,利用热蒸发技术在TiO2薄膜表面沉积了不同厚度的Ag膜,研究了Ag膜厚度对TiO2薄膜结构、形貌、光学和光催化 性能的影响。利 用紫外-可见分光光度计(UV-VIS)、X射线衍射仪(XRD)、冷场发射电子显微镜(SEM)对沉积 后的薄膜分别 进行光学、结构、形貌分析。利用能谱仪测定了元素成分及含量。用光催化降解亚甲基橙(M O)的速率评 价了合成的Ag-TiO2的光催化性能。结果表明:Ag纳米粒子在TiO2表面均匀分布;制备 的Ag修饰多孔TiO2纳米薄膜具有优异的光催化性能。测试结果表明:在250 ℃下制备的T iO2薄膜为无定形结构;随着Ag膜厚度 的增加,样品的光催化活性提高。当Ag膜厚度为3.7 nm时,光催化活 性最高;与纯TiO2相比,Ag-TiO2具有更高的光催化活性。

    Abstract:

    TiO2films were deposited employing electron beam evaporation te chnique on fused silica and Si substrates and silver nanoparticles with different thicknesses were deposi ted on TiO2films surface by thermal evaporation technique.The effect of Ag thickness on the structural,morpholog ical,optical and photocatalytic properties of the nanocomposite thin films was investigated,and these properties were obtained by UV-Vis spectrophotometer,X-ray diffraction (XRD),scanning electronmicroscopy (SEM),respectively.The composition and content of elements were determined by energy dispersive spectrometer.The photocatalytic performanc es of the as-synthesized Ag- TiO2were evaluated in terms of their photodegradation rate of methyl orange ( MO) in an aqueous solution under light.The results show that the Ag nanoparticles are well dispersed on porous Ti O2surface.The as-prepared Ag- decorated porous TiO2films exhibits excellent photocatalytic properties.The r esults indicate that the as- deposited Ag-TiO2thin films are amorphous.It indicates that photocatalytic activity of the samples is enhanced with the thickness of Ag increased until reach to 3.7nm.The Ag-TiO 2films show an enhanced photocatalytic activity compared with pure TiO2fil ms.

    参考文献
    相似文献
    引证文献
引用本文

郝殿中,韩培高,牛明生,孔德胜.银纳米颗粒修饰TiO2薄膜的结构,光学及光催化性能[J].光电子激光,2019,30(4):376~381

复制
分享
文章指标
  • 点击次数:
  • 下载次数:
  • HTML阅读次数:
  • 引用次数:
历史
  • 收稿日期:2018-09-25
  • 最后修改日期:
  • 录用日期:
  • 在线发布日期: 2019-05-28
  • 出版日期:
文章二维码