衬底偏压对HWCVD制备纳米晶硅薄膜结晶性的影响
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(1.常熟理工学院 物理与电子工程学院,江苏 常熟 215500; 2.南京航空航天大学 材料 科学与技术学院,江苏 南京 211100)

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张磊(1983-),男,博士,讲师,主要从事半 导体薄膜材料与光伏器件的研究.

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国家高技术研究发展计划(863)计划(2006AA03Z219),江苏省高校自然科学研究(14KJB480001)、江苏高校优势学科建设工程和和苏州市科技计划(SGZ2013126)资助项目 (1.常熟理工学院 物理与电子工程学院,江苏 常熟 215500; 2.南京航空航天大学 材料 科学与技术学院,江苏 南京 211100)


Effect of substrate bias on the structural properties of nanocrystal line silicon films deposited by hot-wire chemical vapor deposition
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(1.Department of Physics,Changshu Institute of Technology,Changshu 215500,Chi na; 2.College of Materials Science and Technology,Nanjing University of Aerona utics and Astronautics,Nanjing 210016,China)

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    摘要:

    通过在热丝化学气相沉积(HWCVD)制备纳米晶硅 薄膜过程中施加衬底偏压,研 究衬底偏压对HWCVD制备纳米晶硅薄膜结晶性能的影响。利用拉曼(Raman)光谱,X射线 衍射(XRD)和扫描电子显微镜(SEM)对所制备的纳米晶硅薄膜的结构性能进行分析。结果表 明,与未施加衬底偏压的薄膜相比,当衬底偏压为-300V时,薄膜 的晶化率由42.2%升高至 46.2%;当衬底偏压升高至-600V时,晶化率 又降至40.6%;未施加衬底偏压与施加-300V 偏压的纳米晶硅薄膜表面由长约200nm、宽约100nm的晶粒构成,-600V衬底偏压的薄 膜表面晶粒尺寸明显变小,并且出现大量非常细小的晶粒。分析产生上述现象的原因,主要 与 高温热丝发射电子、电子在电场作用下加速运动并与反应气体、基团碰撞发生能量传递有关 。

    Abstract:

    In this paper,the effect of substrate bias on the structural properti es of nanocrystalline silicon films deposited by hot-wire chemical vapor deposition (HWCVD) is studied by adding a direct current (DC) bias between the floated graphite substrate holder and the stainless steel chamber.T he structural properties of the films are analyzed by Raman,X-ray diffraction (XRD) and scanning electron microscop y (SEM).The results show that the crystalline fraction is increased from 42.2% to 46.2% by adding -300V subs trate bias.By further raising the substrate bias to -600V,the crystalline fraction is reduced to 40.6%.The su rface of the nanocrystalline silicon films deposited without and with -300V substrate bias is composed of crystall ites with length of about 200nm and width of about 100nm.While raising the substrate bias to -600V,the grai n size is obviously reduced,and a large number of fine grains appear in the deposited nanocrystalline silicon fi lm.These phenomena are mostly related to the electrons emitted from the hot wires.When the tantalum wires ar e heated to a relatively high temperature,a lot of electrons would be emitted from them.These emitted electr ons are accelerated in the electrical field,transferring the kinetic energy to the reactants by inelastic collisions.

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张磊,沈鸿烈,尤佳毅,钱斌,罗琳琳.衬底偏压对HWCVD制备纳米晶硅薄膜结晶性的影响[J].光电子激光,2015,26(12):2325~2330

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  • 收稿日期:2015-06-16
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  • 在线发布日期: 2016-02-29
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