退火温度对AZO薄膜场发射性能的影响
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叶芸(1977-),女,福建南平人,博士,副研 究员,主要从事场致发射阴极材料方面的研究.

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国家“863”重大专项(2013AA030601)、国家自然科学基金(61106053,61101169)、教育部博士基金(20103514110007)和福建省自然科学基金(2013J01236)资助项目 (福州大学 物理与信息工程学院,福建 福州 350002)


Effect of annealing temperature on field emission properties of AZO thin films
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    摘要:

    以纯度为99.95%、Al2O3为2wt.%的 ZnO-Al2O3金属氧化物为溅射靶材,采用射频(RF)磁控溅射的方法,在玻璃衬 底上制备Al掺杂ZnO(AZO)薄膜,研究其场发射特性和导电性能,并分析了不同的退火温度 对AZO薄膜的形貌、导 电及场发射性能的影响。采用原子力显微镜(AFM)及X射线衍射(XRD)对AZO薄膜表面 形貌与结晶特性 进行测试的结果表明,随着退火温度的升高,AZO薄膜的表面粗糙度随之增大,AZO薄膜的结 晶度变好;场发射 性能研究的结果表明,AZO薄膜的开启电场随着退火温度增加呈先减小后增大的趋势,当 退火温度为300℃时, AZO薄膜样品粗糙度最大,场发射性能最好,开启场强为2.8V/μm, 发光均匀性较好,亮度达到650cd/m2,导电 性能最好,电阻率为5.42×10-4 Ω·cm。

    Abstract:

    Aluminum doped zinc oxide (AZO) thin films were successfully deposited by RF magnetron sputtering method on quartz substrate.High purity ZnO-Al2O3(purity:99.95%,Al2O3:2wt.%) targ et was used as source material.The field emission and electrical conduction characteristics of the AZO films are studied ,and the relationship between the field emission characteristics and the annealing temperature of AZO films is analyzed .The effects of different annealing temperatures on the morphology,electrical conductivity and field emission proper ties of AZO thin films are discussed in detail.The results of atom force microscope (AFM) and X-raydiffraction (XRD) re sults show that all samples are polycrystalline, hexagonal wurtzite structure with oriention in the (002) crystallographic direction,while the surface roughness an d crystallinity of AZO thin films are increased with rising annealing temperature.Meanwhile,the field emission p roperties are improved by annealing at different temperatures.As for the AZO films deposited at the annealing temperatu re of 300℃,the surface roughness is the largest and the field emission characteristics are the best,whose turn-on field is as low as 2.8V/μm.The uniform and stable light emission and excellent conductivity are obtained,where the light lumin ance reaches 650cd/m2and the resistivity is 5.42×10-4 Ω·cm.

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叶芸,蔡寿金,颜敏,陈填源,刘玉会,郭太良,林志贤.退火温度对AZO薄膜场发射性能的影响[J].光电子激光,2014,(1):101~106

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  • 收稿日期:2013-04-17
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