磷光与荧光相结合的多层白色有机发光器件
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杨惠山(1964-),男,福建惠安人,教授, 博士,从事有机发光的研究.

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福建省自然基金资助(2011J01359)、福建省教育厅JK类科研(JK2011043)和泉州市科技局基金(2011G16)资助项目 (泉州师范学院 物理与信息工程学院,福建 泉州 362000) )


White organic light-emitting device based on phosphorescent emissive l ayer combined with fluorescent emitter
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    摘要:

    采用真空热蒸镀的方法制备了磷光与荧光相结合的 多层白色有机电致发光器件(OLED)。将绿 光磷光掺杂染料掺杂到母体CBP中作为绿光发光层;荧光材料 DCM2以亚单层的方式插入Alq3中作为红光发光层;DPVBi为蓝光发光层。器件的结构为ITO /NPB(40nm)/DPVBi(d nm)/CBP:Ir(ppy)38%(5nm)/ Alq3(5nm)/DCM2(0.05nm)/Alq3(45nm)/LiF(1nm)/AI(200nm)。实验中通过改变蓝光发 光层的厚度,得到了高效率的 白光OLED,器件的最大电流效率可达6.75cd/A,最大功率效率达2.67lm/W,最大亮度 达30440cd/m2。此外,当电压从4V变化到14V时色坐标从(0.59,0.39)变化到(0.35,0.38), 基本处于白光区。本文器件的特点在于其性能可以通过简单调整DPVBi的厚度,避免 了使用多掺杂层工艺的复杂性。

    Abstract:

    Generating the broadband white light t ypically requires two or three types of emitters,which increases complication in material selection and device design.In this paper.a white organic light-emitt ing device (WOLED) based on phosphorescent emissive layer combined with fluoresc ent emitter has been fabricated by vacuum deposition method,in which Ir(ppy)3was doped into CBP host as green emitting layer,sub-monolayer DCM2was inserted in the electron transporting layer as red emitting layer,and fluorescent blue m aterial DPVBi was employed in the WOLED,respectively.The structure of the device is ITO/NPB(40nm)/DPVBi(d nm)/CBP:Ir(ppy)38%(5n m)/Alq3(5nm)/DCM2(0.05nm)/Alq3(45nm)/LiF(1nm) /Al(200nm).The efficient WOLED is obtained by varying the thickness of the blue emitting layer.The maximum luminance,electroluminescence (EL) efficiency,p ower efficiency of the device with the thickness of 12nm DPVBi are 30440cd/m2,6.75cd/A,2.67lm/W,respectively.Moreo-ver,the Commi ssion Internationale De L′Eclairage (CIE) coordinates of the device vary from ( 0.59, 0.39) at 4V to (0.35,0.38) at 14V generally within the white region.The p erformance of the WOLED may be tuned by changing the thickness of DPVBi.This app roach is expected to reduce manufacture cost and avoid the complexity of co-dep osition process in thermal evaporation.

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杨惠山,吴丽双,潘玉灼.磷光与荧光相结合的多层白色有机发光器件[J].光电子激光,2013,(4):673~678

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  • 收稿日期:2012-10-06
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